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Single-molecule magnets based on the orbitally-degenerate spin centers and stable organic radicals complexes (VoLuRad)
Date du début: 1 sept. 2014, Date de fin: 31 août 2015,
The finding some polynuclear complexes can behave like magnets on the molecular level attracted much attention, opening perspectives for their applications in processing devices or for high density information storage carriers. To manifest single-molecule magnet (SMM) behaviour a polynuclear complex should have a high-spin ground-state and strong negative anisotropy (D). The energy barrier, U, sep ...
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